期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2021, 期 22, 页码 3340-3344出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202100404
关键词
Asymmetric synthesis; Dihydro-1H-pyrrole; Organocatalysis; Phosphine; Tetrahydropyridine
Phosphine-catalyzed tandem Michael addition/intramolecular Wittig reactions have been developed for the synthesis of chiral compounds. Catalytic and asymmetric P(III)/P(V) processes were implemented using enantiopure chiral phosphines.
Phosphine-catalyzed tandem Michael addition/intramolecular Wittig reactions have been developed for the synthesis of chiral 2,5-dihydro-1H-pyrrole and tetrahydropyridine derivatives. These processes have been rendered catalytic in phosphine, thanks to the in situ reduction of phosphine oxide by phenylsilane. Furthermore, catalytic and asymmetric P(III)/P(V) processes were implemented using enantiopure chiral phosphines.
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