期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2021, 期 22, 页码 3170-3177出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202100473
关键词
Absorption spectroscopy; Organic semiconductors; Regioisomers; Solar cells; Triazatruxene
Two new dumbbell-shaped molecules based on solubilizing and structuring triazatruxene units connected by a central chromophore were synthesized. These molecules exhibited different electronic conjugation pathways, leading to different absorption properties and energy levels, with one showing higher Power Conversion Efficiency (PCE) attributed to internal charge transfer bands.
Two new dumbbell-shaped molecules based on two solubilizing and structuring triazatruxene (TAT) units linked by a central chromophore were synthesized and studied. The central chromophore was an electro-deficient fluorene-malononitrile (FM) unit, that can be functionalized symmetrically on two different positions, giving rise to two positional isomers, called TAT-pFM and TAT-mFM, when the TATs are connected to the 2,7- and 3,6-positions, respectively. The two isomers exhibited different electronic conjugation pathways that drastically affect their absorption properties and energy levels. Moreover, while TAT-pFM was organized in a stable 3D mesomorphic structure from room-temperature to the melting point, TAT-mFM remained crystalline and decomposed before melting. Finally, despite a lower hole mobility, the TAT-mFM exhibited the highest Power Conversion Efficiency (PCE) of about 2 % in organic solar cells. This higher PCE was attributed essentially to the pronounced internal charge transfer band contribution to the charge photogeneration observed in TAT-mFM solar cells.
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