Preparation of composite polyethersulfone membrane containing basalt powder and optimization of the parameters using response surface methodology

In this study, environmental-friendly composite polyethersulfone (PES) membranes based on basalt powder were prepared by phase inversion method. The effects of polymer percentage, the basalt percentage, and the thickness of the membrane were investigated on the distilled water flux, compaction factor, bovine serum albumin (BSA) rejection, contact angle, fouling factor and the parameters were modelled by response surface methodology (RSM). The distilled water flux increased when the basalt was added to the membrane up to 6% percentage of the polymer amount. The blending of basalt also provided resistance against the membrane compaction. The BSA rejection experiments approved the positive effects of basalt on the rejections efficiencies. At higher basalt percentages, the rejection efficiencies increased from 78% at the raw membrane to 99% for the composite membranes had 10% basalt. The adding of basalt to the membranes decreased the contact angles. The hydrophilicity of the membranes contained basalt in their structures was higher than those which had not basalt. By comparison with the neat membranes and the basalt added membrane, it can be said that the basalt increased the flux recovery and decreased the irreversible fouling factors. The basalt increased the antifouling properties for the composite membranes. Finally, the prepared membranes were characterized by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX).

Automated summary

The addition of basalt in the composite membranes increased water flux and BSA rejection efficiency, provided resistance against membrane compaction, decreased contact angles, enhanced hydrophilicity, improved flux recovery, reduced fouling factors, and increased antifouling properties.