Magnetic recyclable heterogeneous catalyst Fe3O4/g-C3N4 for tetracycline hydrochloride degradation via photo-Fenton process under visible light

Antibiotic pollution of water resources is a global problem, and the development of new treatments for destroying antibiotics in water is a priority research. We successfully manufactured recyclable magnetic Fe3O4/g-C3N4 through the electrostatic self-assembly method. Selecting tetracycline (TC) as the target pollutant, using Fe3O4/g-C3N4 and H2O2 developed a heterogeneous optical Fenton system to remove TC under visible light. Fe3O4/g-C3N4 was systematically characterized by SEM, TEM, XRD, FTIR, XPS, DRS, and electrochemical methods. The removal efficiency of 7% Fe3O4/g-C3N4 at pH = 3, H2O2 = 5 mM, and catalyst dosage of 1.0 g/L can reach 99.8%. After magnetic separation, the Fe3O4/g-C3N4 photocatalyst can be recycled five times with minimal efficiency loss. The excellent degradation performance of the prepared catalyst may be attributed to the proper coupling interface between Fe3O4 and g-C3N4 which promotes the separation and transfer of photogenerated electrons. Photogenerated electrons can also accelerate the conversion of Fe3+ to Fe2+, thereby producing more OH. The new Fe3O4/g-C3N4 can be used as a raw material for advanced oxidation of water contaminated by refractory antibiotics.

Automated summary

The study successfully prepared recyclable magnetic Fe3O4/g-C3N4 through electrostatic self-assembly method, and developed a heterogeneous optical Fenton system for tetracycline removal. With a removal efficiency of 99.8% under certain conditions, the Fe3O4/g-C3N4 photocatalyst can be recycled five times with minimal efficiency loss.