A novel maize biochar-based compound fertilizer for immobilizing cadmium and improving soil quality and maize growth

In this study, a novel biochar-based compound fertilizer (BCF) was synthesized with maize straw biomass, diatomite, triple superphosphate and urea at different temperatures (300 degrees C, 450 degrees C, 600 degrees C) and mixture proportions (5:1:1:x and 10:1:1:x). An investigation was conducted into the effects of BCF at low application rates on the immobilization of available cadmium, soil fertility and maize growth. The lab incubation experiments showed that the low doses of BCF (B5PN(x) and B10PN(x)) contributed to a significant reduction of the Cd availability in soil, with the highest reduction rate of available Cd up to 44.13%. Field experiments demonstrated that the low doses (< 0.1%) of BCF(especially for B5PN(600))led to the improvement of soil fertility and maize growth (including maize yield) and the significant reduction of Cd contents in maize grains. The increase of pyrolysis temperature could enhance the biochar adsorption capacity for Cd2+ by increasing both specific surface areas and total pore volume. The modification of urea, diatomite and triple superphosphate played a vital role on cadmium immobilization, soil improvement and maize growth by forming porous adsorption, precipitates or complexation with the increase of functional groups, as well as supplementation of N, P, Si nutrients. This study suggested that the biochar-based compound fertilizer (BCF with a mixture ratio of 5:1:1:x) produced at 600 degrees C could be served as a promising and eco-friendly remediation agent for the arable soils polluted with Cd, with reduction of chemical fertilizers. (C) 2021 Elsevier Ltd. All rights reserved.

Automated summary

In this study, a novel biochar-based compound fertilizer was synthesized and its effects on the immobilization of available cadmium, soil fertility and maize growth were investigated. Results showed that low doses of the compound fertilizer significantly reduced Cd availability in soil and improved soil fertility and maize growth. The increase of pyrolysis temperature enhanced the biochar adsorption capacity for Cd2+ and the modification of urea, diatomite, and triple superphosphate played a vital role in cadmium immobilization, soil improvement, and maize growth.