Transport studies of NaPF6 carbonate solvents-based sodium ion electrolytes

Characterizing fundamental ion transport is necessary for the modification and development of electrolytes. In this study, we investigated the local and bulk transport properties of 1 M NaPF6 in the binary EC:PC (1:1), and ternary 5EC:3PC:2DEC (5:3:2) solvents, as well as their 2 wt.% FEC modulated versions. We determined H-1, F-19 and Na-23 Nuclear Magnetic Resonance (NMR) spin-lattice relaxation time (T-1), self-diffusion coefficient (D), linewidth and chemical shift. These were complimented with density, viscosity and ionic conductivity measurements, all as a function of temperature. Both the viscosity and ionic conductivity displayed VFT behavior and their Walden products showed a dependence on temperature. This coupled with their having the lower Walden products indicated less salt dissociation in the 5EC:3PC:2DEC and 5EC:3PC:2DEC + 2 wt.% electrolytes. NMR D F-19 and Na-23 values for these electrolytes were also similar at 298K indicating cation-anion association, but diverged with increasing temperatures, with that for the anion being greater than the cation. The addition of the FEC provides greater local dynamics for the individual solvents in the less polar electrolyte but appeared to impede that of the ions. (C) 2021 Elsevier Ltd. All rights reserved.

Automated summary

Characterizing fundamental ion transport in various electrolytes, including binary and ternary solvents, revealed temperature-dependent behaviors of viscosity and ionic conductivity. NMR measurements showed cation-anion association at lower temperatures but diverged at higher temperatures, with the addition of FEC impacting local dynamics of solvents and ions differently.