期刊
CORROSION SCIENCE
卷 182, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2021.109287
关键词
Ceramic; Molten salts; High temperature corrosion
资金
- Natural Science Foundation of Shanghai [17ZR1436600]
- National Key Research and Development Program [2017YFA0402803]
- National Natural Science Foundation of China [11304096, 11705264, 52071331]
- Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences [XDA21000000]
- Strategic Priority Research Program of the Chinese Academy of Science [XDA 02004220]
The role of helium ion irradiation in the corrosion of CVD-SiC in molten LiF-NaF-KF salt was studied, showing that it enhances the diffusion of silicon element. Additionally, helium ions also break down Si-C bonds to form defects, further increasing the corrosion of SiC.
The role of helium ion irradiation in the corrosion of CVD-SiC in molten LiF-NaF-KF salt was studied. Results indicate that the corrosion of SiC relates to the diffusion of element Si. Impurities in molten LiF-NaF-KF salt react with SiC to drive the outward diffusion of element Si and graphitic carbon is further formed. Energetic helium ions break down the Si-C bonds to form defects. Slight disorder has little effect on the corrosion of SiC, while the amorphous induced by helium ion irradiation significantly enhances the diffusion of element Si and thus increases the corrosion of SiC.
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