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Biomimetic hydrocarbon oxidation catalyzed by Nonheme Iron(III) complexes with peracids: Evidence for an Fe-V=O species
Sun Hwa Lee et al.
CHEMISTRY-A EUROPEAN JOURNAL (2007)
Spin-crossover in an iron(III)-bispidine-alkylperoxide system
Jochen Bautz et al.
INORGANIC CHEMISTRY (2006)
Kinetics of (porphyrin)manganese(III)-catalyzed olefin epoxidation with a soluble iodosylbenzene derivative
James P. Collman et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2006)
Direct hydrogen-atom abstraction by activated bleomycin: An experimental and computational study
A Decker et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)
Nonheme iron(II) complexes of macrocyclic ligands in the generation of oxoiron(IV) complexes and the catalytic epoxidation of olefins
Yumi Suh et al.
JOURNAL OF INORGANIC BIOCHEMISTRY (2006)
Reactivities of mononuclear non-heme iron intermediates including evidence that lron(III) - Hydroperoxo species is a sluggish oxidant
MJ Park et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)
Mechanistic insights into the reversible formation of iodosylarene-iron porphyrin complexes in the reactions of oxoiron(IV) porphyrin pi-cation radicals and iodoarenes: Equilibrium, epoxidizing intermediate, and oxygen exchange
WJ Song et al.
CHEMISTRY-A EUROPEAN JOURNAL (2006)
A mononuclear alkylperoxocopper(II) complex as a reaction intermediate in the oxidation of the methyl group of the supporting ligand
Masayasu Mizuno et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)
Inverse axial-ligand effects in the activation of H2O2 and ROOH by an Mn-III corrolazine
David E. Lansky et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)
Formation of an aqueous oxoiron(IV) complex at pH 2-6 from a nonheme iron(II) complex and H2O2
Jochen Bautz et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)
A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450
MR Bukowski et al.
SCIENCE (2005)
High-valent nonheme iron.: Two distinct iron(IV) species derived from a common iron(II) precursor
MP Jensen et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Theoretical perspective on the structure and mechanism of cytochrome P450 enzymes
S Shaik et al.
CHEMICAL REVIEWS (2005)
Reaction mechanisms of mononuclear non-heme iron oxygenases
MM Abu-Omar et al.
CHEMICAL REVIEWS (2005)
Oxoiron(IV) porphyrin π-cation radical complexes with a chameleon behavior in cytochrome P450 model reactions
WJ Song et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2005)
Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex
H Furutachi et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)
Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution
CV Sastri et al.
CHEMICAL COMMUNICATIONS (2005)
Spin-state rationale for the peroxo-stabilizing role of the thiolate ligand in superoxide reductase
MR Bukowski et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)
Donor ligand effect on the nature of the oxygenating species in MnIII(salen)-catalyzed epoxidation of olefins:: Experimental evidence for multiple active oxidants
JP Collman et al.
INORGANIC CHEMISTRY (2004)
Dioxygen activation at mononuclear nonheme iron active sites: Enzymes, models, and intermediates
M Costas et al.
CHEMICAL REVIEWS (2004)
Spectroscopic characterization of an FeIV intermediate generated by reaction of XO- (X = Cl, Br) with an FeII complex bearing a pentadentate non-porphyrinic ligand -: Hydroxylation and epoxidation activity
V Balland et al.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2004)
Hydroxylation by the hydroperoxy-iron species in cytochrome P450 enzymes
REP Chandrasena et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
Catalytic sulfoxidation and epoxidation with a Mn(III) triazacorrole: Evidence for a third oxidant in high-valent porphyrinoid oxidations
SHL Wang et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
One oxidant, many pathways: a theoretical perspective of monooxygenation mechanisms by cytochrome P450 enzymes
S Shaik et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2004)
Oxidizing intermediates in cytochrome P450 model reactions
W Nam et al.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY (2004)
Structural insights into nonheme alkylperoxoiron(III) and oxoiron(IV) intermediates by x-ray absorption spectroscopy
JU Rohde et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2004)
Evidence for the formation of an iodosylbenzene(salen)iron active intermediate in a (salen)iron (III)-catalyzed asymmetric sulfide oxidation
KP Bryliakov et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)
Multiple active oxidants in competitive epoxidations catalyzed by porphyrins and corroles
JP Collman et al.
CHEMICAL COMMUNICATIONS (2003)
Catalytic O-O activation chemistry mediated by iron hangman porphyrins with a wide range of proton-donating abilities
LL Chng et al.
ORGANIC LETTERS (2003)
Kinetic isotope effects implicate two electrophilic oxidants in cytochrome P450-catalyzed hydroxylations
M Newcomb et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
Non-heme iron enzymes: Contrasts to heme catalysis
EI Solomon et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2003)
An FeIV=O complex of a tetradentate tripodal nonheme ligand
MH Lim et al.
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2003)
Biomimetic aryl hydroxylation derived from alkyl hydroperoxide at a nonheme iron center.: Evidence for an FeIV=O oxidant
MP Jensen et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
Proton-coupled O-O activation on a redox platform bearing a hydrogen-bonding scaffold
CJ Chang et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)
Crystal structure of naphthalene dioxygenase: Side-on binding of dioxygen to iron
A Karlsson et al.
SCIENCE (2003)
Crystallographic and spectroscopic characterization of a nonheme Fe(IV)=O complex
JU Rohde et al.
SCIENCE (2003)
Hydrogen peroxide-coupled cis-diol formation catalyzed by naphthalene 1,2-dioxygenase
MD Wolfe et al.
JOURNAL OF BIOLOGICAL CHEMISTRY (2003)
Multiple mechanisms and multiple oxidants in P450-catalyzed hydroxylations
M Newcomb et al.
ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS (2003)
Reversible formation of iodosylbenzene-iron porphyrin intermediates in the reaction of oxoiron(IV) porphyrin pi-cation radicals and iodobenzene
W Nam et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)
A stable manganese(V)-oxo corrolazine complex
BS Mandimutsira et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)
Anionic ligand effect on the nature of epoxidizing intermediates in iron porphyrin complex-catalyzed epoxidation reactions
W Nam et al.
INORGANIC CHEMISTRY (2002)
Electronic structure and reactivity of high-valent oxo iron porphyrins
H Fujii
COORDINATION CHEMISTRY REVIEWS (2002)
Electronic structure of high-spin iron(III)-alkylperoxo complexes and its relation to low-spin analogues: Reaction coordinate of O-O bond homolysis
N Lehnert et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Mechanism of reaction of hydrogen peroxide with horseradish peroxidase:: Identification of intermediates in the catalytic cycle
JN Rodríguez-López et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Spectroscopic properties and electronic structure of low-spin Fe(III)-alkylperoxo complexes: Homolytic cleavage of the O-O bond
N Lehnert et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Hangman porphyrins for the assembly of a model heme water channel
CY Yeh et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)
Electronic structure of activated bleomycin: Oxygen intermediates in heme versus non-heme iron
F Neese et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
Multiple active oxidants in cytochrome P-450 model oxidations
JP Collman et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
Participation of two distinct hydroxylating intermediates in iron(III) porphyrin complex-catalyzed hydroxylation of alkanes
W Nam et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
Spectroscopic and theoretical studies of mononuclear copper(II) alkyl- and hydroperoxo complexes: Electronic structure contributions to reactivity
P Chen et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
New insights into the mechanisms of O-O bond cleavage of hydrogen peroxide and tert-alkyl hydroperoxides by iron(III) porphyrin complexes
W Nam et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
Co(III)-alkylperoxo complexes: Syntheses, structure-reactivity correlations, and use in the oxidation of hydrocarbons
FA Chavez et al.
ACCOUNTS OF CHEMICAL RESEARCH (2000)
Evidence for the participation of two distinct reactive intermediates in iron(III) porphyrin complex-catalyzed epoxidation reactions
WO Nam et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)
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