期刊
CHEMICAL ENGINEERING JOURNAL
卷 412, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.128676
关键词
LOV-MnO2; Lattice oxygen vacancies; Structure protector; Supercapacitors
资金
- National Natural Science Foundation of China [51772138, 51572118, 51601082]
- Fundamental Research Funds for the Central Universities [lzujbky2020-59]
- Special Funding for Open and Shared Large-Scale Instruments and Equipments of Lanzhou University
This study demonstrated a versatile recipe combining H-plasma and O-plasma to achieve robust lattice oxygen vacancies in birnessite-MnO2, aiming to enhance its electrochemical energy storage performance. Theoretical calculations revealed facilitated ion intercalation and diffusion kinetics in LOV-MnO2 due to lower energy barriers, leading to exceptional electrochemical performance. Such defect engineering recipes have shown great potential for the development of advanced electrode materials for electrochemical energy storage devices.
Defect engineering has been considered as an efficient strategy to enhance the electrochemical performance of transition metal oxides based energy storage devices. However, the electrochemical activity and stability were greatly determined by the defect located crystal and external environments, which dominate the electrochemical properties of its based electrode. Thus, regulating a defect engineering recipe becomes a vital and direct route to advance the performance of the electrode materials. Herein, a versatile recipe combining the mild H-plasma and O-plasma was demonstrated for prototypical birnessite-MnO2 to achieve the robust lattice oxygen vacancies in birnessite-MnO2 (LOV-MnO2), targeting to boost its electrochemical energy storage performance. Theoretical calculation reveals the facilitated ion intercalation and diffusion kinetics due to the lower energy barrier in the LOV-MnO2. The LOV-MnO2 demonstrates an exceptional electrochemical performance with a specific capacitance as high as 445.1 F g(-1) (at the current density of 1 A g(-1)), and the diffusion-controlled capacitance contribution reaches unprecedented -70% (at a scan rate of 5 mV s(-1)). Besides, the configured symmetrical supercapacitor device LOV-MnO2 //LOV-MnO2 delivers remarkable performance with an energy density of 92.3 Wh kg(-1) at a power density of 1100.3 W kg(-1) with a widen working voltage of 2.2 V. An outstanding cyclic life of 92.2% capacitance retention was also achieved after 10,000 charge-discharge cycles. Such superior electrochemical performance suggests that the proposed defect engineering recipes here will aid in the future development of advanced electrode materials for electrochemical energy storage devices.
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