4.7 Article

The use of plastic waste as carbon raw materials to obtain TiC-based powders

期刊

CERAMICS INTERNATIONAL
卷 47, 期 15, 页码 21140-21146

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.04.117

关键词

Plastic recycling; Combustion; Reaction mechanism; Titanium carbide; Phase composition; Structure

资金

  1. Ministry of Science and Higher Education of the Russian Federation [0721-20200028]

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Plastic pollution is a major environmental issue, and efforts are being made to recycle plastic waste into high-purity titanium carbide. The mechanism involves the decomposition of polyethylene terephthalate to form titanium carbide, releasing titanium oxycarbide and carbon dioxide.
Plastic pollution is one of the most pressing environmental problems, and a huge amount of effort and money is directed towards solving it. The existing processing methods are ineffective. The main component of all plastic materials (CxHy) is carbon. High-purity fine titanium carbide was obtained using plastic waste (polyethylene terephthalate - C10H8O4) as a carbon raw material. Combustion processes, phase composition and structure of the obtained materials were studied. A probable mechanism for the formation of titanium carbide during the combustion of the (Ti + C10H8O4) mixture was proposed. During the synthesis, polyethylene terephthalate decomposes into carbon, hydrogen and oxygen. Carbon and oxygen react with titanium and form titanium oxycarbide. Titanium oxycarbide is saturated with carbon to form titanium carbide and carbon dioxide. The remaining hydrogen and carbon dioxide are released from the synthesis products, which leads to self-purification of the synthesis products. The obtained results will create the basis for the development of a fundamentally new, cost-effective technology for recycling plastic waste into carbides and carbide-containing materials.

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