4.7 Article

Effect of dopant concentration and annealing temperature on electric and magnetic properties of lanthanum substituted CoFe2O4 nanoparticles for potential use in 5G wireless communication systems

期刊

CERAMICS INTERNATIONAL
卷 47, 期 14, 页码 20669-20677

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ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.04.077

关键词

Spinel ferrites; Dielectric properties; Magnetic properties; 5G wireless communication system

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The study focuses on synthesizing Lanthanum-doped cobalt ferrite nanoparticles for high-frequency devices in 5G telecommunication systems. These nanoparticles exhibit enhanced magnetic and dielectric properties, making them suitable for applications in wireless communication. The inclusion of rare-earth ions and high annealing temperatures significantly affect the magnetic and dielectric properties of the ferrite nanoparticles.
Dielectric-magnetic nanoparticles are the key component used in high-frequency devices employed in the 5G telecommunication system. Lanthanum-doped cobalt ferrites have shown remarkable properties to improve the functioning of the wireless system. In this context, CoLaXFe2-XO4 (x = 0, 0.025, 0.050, 0.075, 0.1) ferrite nanoparticles are synthesized using chemical coprecipitation technique. X-ray diffraction confirms cubic spinel structure with average crystallite size ranging from 17 to 42 nm. Fourier transform infrared spectra exhibit a characteristic band at similar to 575 cm(-1) illustrating the formation of the ferrite phase. Magnetic properties show a nonlinear variation with La3+ ions content as well as annealing temperature attributed to the complex inclusion mechanism involved in the substitution of Fe3+ ions by rare-earth ions. The formation of secondary phases at high annealing temperature had a significant effect on magnetic and dielectric properties. Saturation magnetization ranges from 21.6emu/g to 49.6emu/g and shows an increasing trend with annealing. The Nyquist plots indicate the dominant effect of grain boundaries in the conduction process. The La-doped annealed ferromagnetic ferrites possess a good crystalline structure with enhanced dielectric constant, high anisotropy constant, moderate saturation magnetization, and high Q-factor which makes them a superior choice in 5G wireless communication system.

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