4.6 Article

Aerobic photoxidation of sulfides using unique hybrid polyoxometalate under visible light

期刊

CATALYSIS COMMUNICATIONS
卷 152, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.catcom.2021.106283

关键词

Polyoxometalate; Hybrid compounds; Photocatalyst; Aerobic oxidation; Sulfide oxidation

资金

  1. University of Isfahan
  2. Islamic Azad University-Central Tehran Branch

向作者/读者索取更多资源

A unique hybrid Polyoxometalate with the ability to absorb visible light and perform photocatalytic activity was synthesized. By utilizing this material, the photooxidation of sulfides under O2 atmosphere was conducted, leading to the synthesis of corresponding sulfoxide products in good to high yields.
A unique hybrid Polyoxometalate was synthesized, which can absorb visible light and perform photocatalytic activity. This Organic-Inorganic hybrid material was synthesized through attaching the organotin compound to the vacant polyoxometalate. Interestingly, this hybridization brought an outstanding decrement in the polyoxometalate band gap and turned this hybrid polyoxometalate to a photocatalytic compound, which can conduct catalytic reactions under visible light. In this line, we devised photoxidation of sulfides using this photocatalyst and under O-2 atmosphere as a sustainable and environmental friendly oxidant. Various kinds of sulfides were investigated under optimum reaction conditions and the corresponding sulfoxide products were synthesized in good to high yields.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据