期刊
CATALYSIS COMMUNICATIONS
卷 152, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.catcom.2021.106292
关键词
Syngas conversion; MOF-derived oxide; Light olefins; SAPO-34
资金
- National High-Tech R&D Program of China [2011AA05A204]
The study demonstrates that MOF-derived ZnZrOx nanoparticles, when used as a component of bifunctional catalysts, exhibit enhanced CO conversion and olefins selectivity when combined with SAPO-34.
ZnZrOx nanoparticles were prepared by MOF calcination and co-precipitation methods and used as metal oxide components of bifunctional catalysts for syngas-to-olefins (STO). The results of characterization analysis, like XRD, XPS, H-2-TPR and CO-TPD, illustrated that different preparation methods apparently influenced surface chemistry properties of oxides. MOF-derived oxides possessed abundant oxygen vacancies and Zn-O-Zr local structure which were beneficial to CO activation and the formation of methanol and dimethyl ether. When combining with SAPO-34, the bifunctional catalysts containing MOF-derived ZnZrOx achieved 22.5% CO conversion and 79.7% light olefins selectivity among hydrocarbons.
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