Vapor phase polymerization for electronically conductive nanopaper based on bacterial cellulose/poly(3,4-ethylenedioxythiophene)

Eco-friendly conductive polymer nanocomposites have garnered attention as an effective alternative for conventional conductive nanocomposites. Here, we report the fabrication and optimization of flexible, self-standing, and conductive bacterial cellulose/poly(3,4-ethylene dioxythiophene) (BC/PEDOT) nanocomposites using the vapor phase polymerization (VPP) method. Eco-friendly bacterial cellulose (BC) is used as a flexible matrix, and the highly conductive PEDOT polymer is introduced into the BC matrix to achieve electronic conductivity. We demonstrate that vapor phase polymerized BC/PEDOT composites exhibit more than 10 times lower sheet resistance (18 Omega/square) compared to solution polymerized BC/PEDOT (188 Omega/square). The resultant BC/PEDOT fabricated could be bent up to 100 times and completely rolled up without a notable decrease in electronic performance. Moreover, bent BC/PEDOT films enable operation of a green light-emitting diode (LED) light, indicating the flexibility and stability of conductive BC/PEDOT films. Overall, this study suggests a strategy for the development of eco-friendly, flexible, and conductive nanocomposite films.

Automated summary

The BC/PEDOT composites fabricated by vapor phase polymerization exhibit significantly lower sheet resistance than solution polymerized BC/PEDOT, while maintaining good flexibility and stability. They can be used to power green light-emitting diode (LED) lights, demonstrating excellent electronic performance.