Effect of Fe-N modification on the properties of biochars and their adsorption behavior on tetracycline removal from aqueous solution

Tetracycline (TC) adsorption capacity on pristine biochar was limited. Biochar modification can greatly improve its adsorption amount. In this study, rice straw was mixed with FeCl3 center dot 6H(2)O and urea to prepare a Fe-N modified biochar via a one-pot pyrolysis method at 700 degrees C. Meanwhile, pristine biochar (RSBC), urea modified biochar (N-RSBC), FeCl3 center dot 6H(2)O-modified biochar (Fe-RSBC) were produced as control. More functional groups, more graphited carbon structure, and magnetic components were observed in Fe-N-RSBC. Compared with RSBC, the surface area, total pore and micropore volume of Fe-N-RSBC increased 3.4-fold, 3.0-fold and 2.3-fold, respectively. The maximum capacity of TC adsorption on Fe-N-RSBC reached 156 mg.g(-1), which was 5.4 - fold, 8.2 - fold and 1.9 - fold increase to that of RSBC, N-RSBC, Fe-RSBC, respectively. The mechanism of TC adsorption on Fe-N-RSBC involved pore filling, hydrogen-bond interaction, surface complexation, and pi-pi interaction. Therefore, Fe-N-RSBC can be used as an effective adsorbent for TC removal from aqueous solution.

Automated summary

The study demonstrated that Fe-N modified biochar produced by mixing rice straw with FeCl3·6H2O and urea showed enhanced adsorption capacity for TC due to the presence of more functional groups and increased surface area and pore volume. The adsorption mechanism of TC on Fe-N-RSBC involved pore filling, hydrogen-bond interaction, surface complexation, and pi-pi interaction. Fe-N-RSBC can be effectively used as an adsorbent for TC removal from aqueous solution.