Adsorption of copper (II) in aqueous solution using biochars derived from Ascophyllum nodosum seaweed

There has been growing research interest in exploiting biochar for cost-effective. removal of different pollutants. Heavy metals, especially copper II (Cu II) is highly toxic and nonbiodegradable pollutants, and has been major source of environmental pollution. In this study adsorption of Cu (II) on seaweed (Ascophyllum nodosum)-derived biochar was systematically examined. The removal efficiency based on surface property of biochar and type of interactions associated with biochar produced at varying pyrolysis conditions were investigated. The highest removal efficiency of Cu (II) from aqueous media was >99% with 223 mg g(-1) Cu (II) adsorption capacity observed by biochar derived at 700 degrees C and pH 5. Langmuir adsorption isotherm described the adsorption mechanisms of Cu (II) on biochar with cationic and anionic electrostatic attractions, surface precipitation, and pore depositions. Thus, this study shows that waste biomass (seaweed) could be a valuable bioresource for heavy metal remediation from various water bodies.

Automated summary

This study found that seaweed-derived biochar showed high removal efficiency for Cu(II) in water, with Langmuir adsorption isotherm explaining the adsorption mechanisms. This indicates that waste biomass (seaweed) could be a valuable biological resource for removing heavy metals from various water bodies.