期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 283, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2020.119610
关键词
Silica supported iron oxide; Polyol; Sulfuric acid decomposition; alpha-Fe2O3; Hydrogen generation
The study focused on addressing the issues of catalytic activity and stability of the Fe2O3/SiO2 catalyst using different preparation methods. The catalysts showed varying properties and the sample prepared by polyol method exhibited higher activity and stability.
To address the issues of catalytic activity and stability of the promising Fe2O3/SiO2 catalyst for sulfuric acid decomposition, Fe2O3 was immobilized on SiO2 support by polyol, solvothermal and wet-impregnation methods and examined. The different methods yielded catalysts with varying crystal structure, porosity, morphology and redox properties which were investigated by XRD, Modssbauer spectroscopy, N-2-BET surface area, SAXS, ED-XRF, HR-TEM, TPR/O and XPS techniques. The effect of the properties on the activity and stability was evaluated in a fixed-bed reactor and a structure-activity correlation was established. Above 750 degrees C the catalytic activity followed the order polyol > wet impregnation similar to solvothermal. Stability of the sample prepared by polyol method was ascertained by 100 h experimental run at 800 degrees C. The higher activity and stability of the Fe2O3/SiO2 catalyst (polyol) is ascribed to the development of crystalline alpha-Fe2O3 dispersed phase, higher pore confinement, better support-active phase interactions and higher degree of reduction.
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