期刊
ANNUAL REVIEW OF MATERIALS RESEARCH, VOL 51, 2021
卷 51, 期 -, 页码 73-99出版社
ANNUAL REVIEWS
DOI: 10.1146/annurev-matsci-080619-101319
关键词
polymer electrolytes; polyelectrolytes; conjugated polymers; conducting polymers; mixed conductor; mixed transport
资金
- Swedish Research Council [2016-03979]
- Olle Engkvists Stiftelse [204-0256]
- Advanced Functional Materials Center at Linkoping University [2009-00971]
- National Science Foundation [NSF DMR-1751308]
- Alfred P. Sloan Foundation
- Swedish Research Council [2016-03979] Funding Source: Swedish Research Council
Polymeric MIECs combine aspects of ionic and electronic transport with different mechanisms and functionalities, but they are surprisingly tunable independently. This material has a wide range of applications, opening up new possibilities in energy storage and conversion, bioelectronics, and display technologies.
Polymeric mixed ionic-electronic conductors (MIECs) combine aspects of conjugated polymers, polymer electrolytes, and polyelectrolytes to simultaneously transport and couple ionic and electronic charges, opening exciting new applications in energy storage and conversion, bioelectronics, and display technologies. The many applications of polymeric MIECs lead to a wide range of transport conditions. Ionic and electronic transport are directly coupled through electrochemical doping, while the mechanisms of ionic and electronic transport depend on distinctly different chemical functionality, (macro)molecular structure, and morphology. Despite this, ionic and electronic transport are surprisingly tunable, independent of one another. We review the various types of polymeric MIECs, the mechanisms of ionic and electronic charge transport across conditions, and the interrelations between the two, with special emphasis on the unique aspects of polymeric MIEC transport phenomena.
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