4.8 Article

Bottom-up Fabrication and Atomic-Scale Characterization of Triply Linked, Laterally π-Extended Porphyrin Nanotapes**

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Summary: On-surface synthesis is a powerful tool for constructing large, planar, pi-conjugated structures that are inaccessible through standard solution chemistry, with graphene nanoribbons (GNRs) holding a prime position in nanoelectronics due to their outstanding properties. Using appropriately designed molecular precursors allows the synthesis of functionalized GNRs, leading to nanostructured hybrids with superior physicochemical properties. Porphyrins (Pors) stand out among potential partners for GNRs due to their rich chemistry, robustness, and electronic richness, but constructing GNR hybrids with such pi-conjugated macrocycles is challenging and examples are scarce.

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