期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 24, 页码 13548-13553出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202017274
关键词
optical waveguides; organic– inorganic metal-halide materials; polarized emission; quantum efficiency; zero-dimensional structure
资金
- National Natural Science Foundation of China [21373097, 51872114]
- National Basic Research Program of China [21932003]
- DST Nanomission, India [DST/NM/NS/2018/18]
- CSIR-HRDG, India
- IACS, India
In this study, single-crystal microrods and microplates of one-dimensional (DTA)(2)SbCl5.DTAC were successfully prepared with a 0D structure, exhibiting a broadband orange emission peak with a high photoluminescence quantum yield and a large Stokes shift under photoexcitation. The microrods showed an optical waveguide effect with low loss coefficient and linear polarized photoemission.
Organic-inorganic metal-halide materials (OIMMs) with zero-dimensional (0D) structures offer useful optical properties with a wide range of applications. However, successful examples of 0D structural OIMMs with well-defined optical performance at the micro-/nanometer scale are limited. We prepared one-dimensional (1D) (DTA)(2)SbCl5.DTAC (DTAC=dodecyl trimethyl ammonium chloride) single-crystal microrods and 2D microplates with a 0D structure in which individual (SbCl5)(2-) quadrangular units are completely isolated and surrounded by the organic cation DTA(+). The organic molecular unit with a long alkyl chain (C-12) and three methyl groups enables microrod and -plate formation. The single-crystal microrods/-plates exhibit a broadband orange emission peak at 610 nm with a photoluminescence quantum yield (PLQY) of ca. 90 % and a large Stokes shift of 260 nm under photoexcitation. The broad emission originates from self-trapping excitons. Spatially resolved PL spectra confirm that these microrods exhibit an optical waveguide effect with a low loss coefficient (0.0019 dB mu m(-1)) during propagation, and linear polarized photoemission with a polarization contrast (0.57).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据