期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 39, 页码 21150-21172出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202101667
关键词
carboxylation; CO2 reduction; coupling strategies; photocatalysis; organic synthesis
资金
- National Natural Science Foundation of China [22072023, 21872029, U1463204]
- Program for National Science and Technology Innovation Leading Talents [00387072]
- Program of Fujian Province for Top Creative Young Talents
- Program for Leading Talents of Fujian Universities
- Natural Science Foundation of Fujian Province [2017J07002, 2019J0106]
- Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials (Wuhan University of Science and Technology)
- Natural Science Foundation of Hubei Province [2020CFB124]
The photocatalytic reduction of CO2 to solar fuels and fine chemicals is a promising approach to increase energy supply and reduce greenhouse gas emissions. Recent developments integrating CO2 valorization with selective organic synthesis into one reaction system show efficient utilization of photogenerated electrons and holes for sustainable economic and social development goals.
Photocatalytic reduction of CO2 to solar fuels and/or fine chemicals is a promising way to increase the energy supply and reduce greenhouse gas emissions. However, the conventional reaction system for CO2 photoreduction with pure H2O or sacrificial agents usually suffers from low catalytic efficiency, poor stability, or cost-ineffective atom economy. A recent surge of developments, in which photocatalytic CO2 valorization is integrated with selective organic synthesis into one reaction system, indicates an efficient modus operandi that enables sufficient utilization of photogenerated electrons and holes to achieve the goals for sustainable economic and social development. In this Review we discuss current advances in cooperative photoredox reaction systems that integrate CO2 valorization with organics upgrading based on heterogeneous photocatalysis. The applications and virtues of this strategy and the underlying reaction mechanisms are discussed. The ongoing challenges and prospects in this area are critically discussed.
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