期刊
ADVANCED FUNCTIONAL MATERIALS
卷 31, 期 25, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202101285
关键词
bidirectional catalysts; hierarchical structures; lithium‐ sulfur batteries; NiMoO; (4) nanosheets; N; S doped carbon clothes
类别
资金
- National Key Research and Development Program of China [2018YFB0104200]
- Hunan Provincial Education Office Foundation of China [20B570]
- Hunan Provincial Natural Scientific Foundation of China [2017JJ3297]
- Scientific Research Projects of Hunan Provincial Strategic Emerging Industries [2016GK4030]
- Scientific Research Fund of Xiangtan University [2018HJYH08, 2015SEP03, 13QDZ30, 2014XZX07, 2018ZKKF03]
A 3D hierarchical structure composed of NiMoO4@NSCC self-supporting cathode is successfully designed and constructed to address the shuttle effect and reduction/oxidation reactions in Li-S batteries, demonstrating impressive long cycle stability.
The serious shuttle effect, sluggish reduction kinetics of polysulfides and the difficult oxidation reaction of Li2S have hindered Li-S battery practical application. Herein, a 3D hierarchical structure composed of NiMoO4 nanosheets in situ anchored on N-S doped carbon clothes (NiMoO4@NSCC) as the free-standing host is creatively designed and constructed for Li-S battery. Dual transitional metal oxide (NiMoO4) increases the electrons density near the Fermi level due to the contribution of the incorporating molybdenum (Mo), leading to the smaller bandgap, and thus stronger metallic properties compared with NiO. Furthermore, as a bidirectional catalyst, NiMoO4 is proposed to facilitate reductions of polysulfides through lengthening the S-S bond distance of Li2S4 and reducing the free energy of polysulfides conversion, meanwhile promote critical oxidation of insulative discharge product (Li2S) via lengthening Li-S bond distance of Li2S and decreasing Li2S decomposition barrier. Therefore, after loading sulfur (2 mg cm(-2)), NiMoO4@NSCC/S as the self-supporting cathode for the Li-S battery exhibits impressive long cycle stability. This study proposes a concept of a bidirectional catalyst with dual metal oxides, which would supply a novel vision to construct the high-performance Li-S battery.
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