4.8 Article

Covalent Coupling-Stabilized Transition-Metal Sulfide/Carbon Nanotube Composites for Lithium/Sodium-Ion Batteries

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Summary: Although some transition metal oxide-based electrodes exhibit high storage capacities beyond theoretical values, the surface capacitance on metal nanoparticles involving spin-polarized electrons is consistent with a space charge mechanism. The phenomenon of anomalously high storage capacities in different metal oxides is still under debate, but in situ magnetometry has shown that surface capacitance plays a dominant role in providing extra capacity. This space charge mechanism can be generalized to a broad range of transition metal compounds, providing guidance for advanced energy storage systems.

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