Arylazopyrazole-Based Dendrimer Solar Thermal Fuels: Stable Visible Light Storage and Controllable Heat Release

Solar thermal fuels offer a closed cycle and a renewable energy storage strategy by harvesting photon energy within the chemical conformations of molecules and retrieving energy by an induced release of heat. However, the majority of reports are limited to the ultraviolet light storage, which potentially interferes with the surrounding environment and reduces the material lifetime. Here, we present a novel arylazopyrazole (AAP)-containing dendrimer that not only addresses the hindrance of visible light storage for solar thermal fuels but also exhibits outstanding performances of abundant energy conversion and stable storage, which are attributed to the substantial absorbance in visible wavelengths of para-thiomethyl-substituted AAP groups and the stability of cis isomers, respectively. The energy density of the dendrimer fuel after efficiently harvesting blue light (405 nm) is as high as 0.14 MJ kg(-1) (67 kJ mol(-1)), and the storage half-life of the fabricated dendrimer film can reach up to 12.9 days. Moreover, the heat release of the dendrimer film can be triggered by different stimuli (light and heat). The dendrimer film displays a 6.5 degrees C temperature difference between trans isomers and cis isomers during green light irradiation. Our work provides a fascinating avenue to fabricate visible light storage solar thermal fuels and unlocks the possibility of developing natural sunlight storage in the future.

Automated summary

Solar thermal fuels provide a renewable energy storage strategy by harvesting photon energy within molecules and retrieving energy through the release of heat. A novel arylazopyrazole (AAP)-containing dendrimer has been developed to address the hinderance of visible light storage, showing high energy conversion and stable storage performance.