Harvesting triplet excitons for near-infrared electroluminescence via thermally activated delayed fluorescence channel

Near-infrared (NIR) emission is useful for numerous practical applications, such as communication, biomedical sensors, night vision, etc., which encourages researchers to develop materials and devices for the realization of efficient NIR organic light-emitting devices. Recently, the emerging organic thermally activated delayed fluorescence (TADF) emitters have attracted wide attention because of the full utilization of electron-generated excitons, which is crucial for achieving high device efficiency. Up to now, the TADF emitters have shown their potential in the deep red/NIR region. Considering the color purity and efficiency, however, the development of NIR TADF emitters still lags behind RGB TADF emitters, indicating that there is still much room to improve their performance. In this regard, this perspective mainly summarizes the past progress of molecular design on constructing TADF NIR emitters. We hope this perspective could provide a new vista in developing NIR materials and enlighten breakthroughs in both fundamental research and applications.

Automated summary

Near-infrared (NIR) emission is widely used in communication, biomedical sensors, and night vision, while organic thermally activated delayed fluorescence (TADF) emitters have attracted attention for their efficient utilization of excitons. However, the development of NIR TADF emitters lags behind RGB TADF emitters in terms of performance improvement.