A system coupling hybrid biological method with UV/O3 oxidation and membrane separation for treatment and reuse of industrial laundry wastewater

The possibilities of application of a three-step system combining hybrid biological treatment followed by advanced UV/O-3 oxidation with in situ generated O-3 and membrane separation (ultrafiltration (UF) and nanofiltration (NF)) to treat and reuse the wastewater from an industrial laundry are presented. By the application of a hybrid moving bed biofilm reactor (HMBBR), the total organic carbon concentration was reduced for about 90 %. However, since the HMBBR effluent still contained organic contaminants as well as high concentrations of inorganic ions and exhibited significant turbidity (8.2 NTU), its further treatment before a possible reuse in the laundry was necessary. The UV/O-3 pretreatment prior to UF was found to be an efficient method of the membrane fouling alleviation. During UF, the turbidity of wastewater was reduced below 0.3 NTU. To remove the inorganic salts, the UF permeate was further treated during NF. The NF permeate exhibited very low conductivity (27-75 mu S/cm) and contained only small amounts of Ca2+ and Mg2+; thus ,it could be reused at any stage of the laundry process.