Microencapsulation of fatty acid eutectic with polyvinyl chloride shell used for thermal energy storage

MEPCMs have drawn tremendous attention in TES fields. In this study, eutectic of CA and PA was encapsulated by PVC, and the novel MEPCM for TES applications was developed. Microcapsules were prepared by solvent evaporation method and examined using DSC, SEM, LPSA, FTIR, thermal cycling test and TGA. DSC results demonstrated that the phase change temperature of CA-PA eutectic decreased after microencapsulation. The most satisfied sample was the MEPCM with a shell-core ratio of 1:2, which melted at 17.1 degrees C with the latent heat of 92.1 J/g, the encapsulation ratio was 57.7%. SEM images and LPSA results showed that the prepared MEPCMs were consisted with micro-sized spheres. FTIR results confirmed that the PCM core was successfully encapsulated by the PVC shell, and no chemical reaction was found among the components. The prepared MEPCM showed an excellent thermal reliability after 500 times of thermal cycling. Microencapsulation enhanced the starting temperature of CA-PA eutectic thermal decomposition, and the novel MEPCM exhibited an excellent thermal stability at working temperature from TGA results. Consequently, MEPCM (1:2) was the optimal composition and had great potential for TES applications.

Automated summary

MEPCMs have attracted significant attention in TES fields. A novel MEPCM for TES applications was developed by encapsulating eutectic of CA and PA with PVC. The optimal composition, with a shell-core ratio of 1:2, exhibited a melting point of 17.1 degrees C, latent heat of 92.1 J/g, and encapsulation ratio of 57.7%. Microencapsulation improved the thermal stability and starting temperature of the eutectic, showing great potential for TES applications.