Thickness-Dependent Piezoelectric Property from Quasi-Two-Dimensional Zinc Oxide Nanosheets with Unit Cell Resolution

A quantitative understanding of the nanoscale piezoelectric property will unlock many application potentials of the electromechanical coupling phenomenon under quantum confinement. In this work, we present an atomic force microscopy- (AFM-) based approach to the quantification of the nanometer-scale piezoelectric property from single-crystalline zinc oxide nanosheets (NSs) with thicknesses ranging from 1 to 4nm. By identifying the appropriate driving potential, we minimized the influences from electrostatic interactions and tip-sample coupling, and extrapolated the thickness-dependent piezoelectric coefficient (d(33)). By averaging the measured d(33) from NSs with the same number of unit cells in thickness, an intriguing tri-unit-cell relationship was observed. From NSs with 3n unit cell thickness (n = 1, 2, 3), a bulk-like d(33) at a value of similar to 9pm/V was obtained, whereas NSs with other thickness showed a similar to 30% higher d(33) of similar to 12pm/V. Quantification of d33 as a function of ZnO unit cell numbers offers a new experimental discovery toward nanoscale piezoelectricity from nonlayered materials that are piezoelectric in bulk.

Automated summary

Quantitative measurement of the nanoscale piezoelectric property of single-crystalline zinc oxide nanosheets revealed an intriguing tri-unit-cell relationship, with different thicknesses showing variations in the piezoelectric coefficient. The study offers a new experimental discovery towards nanoscale piezoelectricity from nonlayered materials that are piezoelectric in bulk.