Atomic nonaffinity as a predictor of plasticity in amorphous solids

Structural heterogeneity of amorphous solids presents difficult challenges that stymie the prediction of plastic events, which are intimately connected to their mechanical behavior. Based on a perturbation analysis of the potential energy landscape, we derive the atomic nonaffinity as an indicator with intrinsic orientation, which quantifies the contribution of an individual atom to the total nonaffine modulus of the system. We find that the atomic nonaffinity can efficiently characterize the locations of the shear transformation zones, with a predicative capacity comparable to the best indicators. More importantly, the atomic nonaffinity, combining the sign of the third-order derivative of energy with respect to coordinates, reveals an intrinsic softest shear orientation. By analyzing the angle between this orientation and the shear loading direction, it is possible to predict the protocol-dependent response of one shear transformation zone. Employing this method, the distribution of orientations of shear transformation zones in model two-dimensional amorphous solids can be measured. The resulting plastic events can possibly be understood from a simple model of independent plastic events occurring at variously oriented shear transformation zones. These results shed light on the characterization and prediction of the mechanical response of amorphous solids.

Automated summary

Research has shown that atomic nonaffinity is an effective indicator for describing the position of shear transformation zones and predicting plastic events, with high predictive capacity. Furthermore, by analyzing the angle between atomic nonaffinity and the shear loading direction, it is possible to predict the protocol-dependent response of shear transformation zones.