4.6 Article

Hypothesis on the Influence of the Magnetic Behaviour of Hydrogen Doped Zinc Oxide during Its Plasma Sputtering Process

期刊

COATINGS
卷 11, 期 2, 页码 -

出版社

MDPI
DOI: 10.3390/coatings11020222

关键词

sputtering; zinc oxide; magnetic; TCO; hydrogen doping

资金

  1. Grand Challenge Research Fund (GCRF)/EPSRC toward the SUNRISE program [EP/P032591/1]
  2. EPSRC [EP/P032591/1] Funding Source: UKRI

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The study focuses on the complexity of reactive sputtering of highly conductive zinc oxide thin films with hydrogen at room temperature. Precise geometric positioning of the substrate relative to the magnetron is crucial for achieving maximum conductivity. The electrical properties of deposited thin films are examined based on their position with respect to the magnetron on the substrate holder.
We investigate the complexity of the reactive sputtering of highly conductive zinc oxide thin films in the presence of hydrogen at room temperature. We report on the importance of precise geometric positioning of the substrate with respect to the magnetron to achieve maximum conductivity. We examine the electrical properties of the deposited thins films based on their position on the substrate holder relative to the magnetron. By considering early reports by other researchers on the angular dependency of plasma parameters and the effect of hydrogen doping on electric and magnetic properties of hydrogen-doped zinc oxide, we propose a hypothesis on the possibility of such properties resulting in the observations presented in this report pending further tests to verify this hypothesis. Overall, in this report we present the guide by which highly conductive zinc oxide thin film coatings can be prepared via RF sputtering with hydrogen presence along with argon as the sputtering gas.

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