期刊
RESULTS IN PHYSICS
卷 22, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.rinp.2021.103893
关键词
Core-shell nanoparticles; Metal organic chemical vapor deposition; Thermal stability; Magnetic property; Magnetic alloy
资金
- National Natural Science Foundation of China [12072111, 11674399]
- Hunan Provincial Natural Science Foundation of China [2020JJ4676]
- Changsha Municipal Natural Science Foundation [kq2007002]
This study presents a one-step method for synthesizing magnetic alloy-C core-shell nanoparticles with tunable elemental components, showing performance variations under different Co/Ni molar ratios. These nanoparticles exhibit stability at low temperatures and slight oxidation at higher temperatures.
Magnetic alloy-C core-shell nanoparticles with tunable elemental components are highly expected for their controllable magnetic, catalytic, and electromagnetic properties, and high air stability. Here we present a simple one-step metal organic chemical vapor deposition for the synthesis of CoNi-C core-shell nanoparticles with tunable Co/Ni molar ratio. The as-synthesized nanoparticles have core sizes of 5-50 nm, shell thicknesses of similar to 5 nm, and tunable Co/Ni molar ratio determined by the molar ratio of Co(acac)(3)/Ni(acac)(2) used in the precursor. The core-shell nanoparticles are very stable in ambient atmosphere at the temperature below 200 degrees C, and exhibit a slight oxidation in the temperature range of 200-400 degrees C. The core-shell nanoparticles with Co/Ni molar ratios of 1.27:1, 0.64:1, and 0.30:1 exhibit saturation magnetization values of 41, 31, and 24 emu/g, and coercivity values of 483, 346, and 362 Oe, respectively. It is demonstrated that the microwave absorption parameters of the as-synthesized nanoparticles can be tuned by the Co/Ni molar ratio, which provides a practical strategy to regulate the microwave absorption properties of nanostructured absorbers.
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