Effect of Fe on the Microstructure and Mechanical Properties of Fe/FeAl2O4 Cermet Prepared by Hot Press Sintering

The Fe/FeAl2O4 cermet was prepared with Fe-Fe2O3-Al2O3 powder by a hot press sintering method at 1400 degrees C. The raw materials for the powder particles were respectively 2 mu m (Fe), 0.5 mu m (Fe2O3), and 0.5 mu m (Al2O3) in diameter, the sintering pressure was 30 MPa, and the holding time was 120 min. The effects of different Fe mass ratios on the microstructure and mechanical properties of Fe/FeAl2O4 cermet were studied. The results showed that a new ceramic phase FeAl2O4 could be formed by an in situ reaction during the hot press sintering. When the Fe mass ratio was increased, the microstructure and mechanical properties of the Fe/FeAl2O4 cermet showed a change law that initially became better and then became worse. The best microstructure and mechanical properties were obtained in the S2 sample, where the mass ratio of Fe-Fe2O3-Al2O3 was 6:1:2. In this Fe mass ratio, the relative density was about 94%, and the Vickers hardness and bending strength were 1.21 GPa and 210.0 MPa, respectively. The reaction mechanism of Fe in the preparation process was the in situ synthesis reaction of FeAl2O4 and the diffusion reaction of Fe to FeAl2O4 grains. The increase of the Fe mass ratio improved the wettability of Fe and FeAl2O4, which increased the diffusion rate of Fe to FeAl2O4 grains, which increased the influence on the structure of FeAl2O4.

Automated summary

Fe/FeAl2O4 cermet was prepared using a hot press sintering method, forming a new ceramic phase FeAl2O4 during the process. The microstructure and mechanical properties showed an initial improvement followed by deterioration as the Fe mass ratio increased, with the best performance observed at a ratio of 6:1:2. Increasing the Fe mass ratio enhanced Fe and FeAl2O4 wettability, leading to improved diffusion rate and structural influence on FeAl2O4.