Promoting the Reversible Oxygen Redox Reaction of Li-Excess Layered Cathode Materials with Surface Vanadium Cation Doping

Li-excess layered cathode (LLC) materials have a high theoretical specific capacity of 250 mAh g(-1) induced by transition metal (cationic) and oxygen (anionic) redox activity. Especially, the oxygen redox reaction related to the activation of the Li2MnO3 domain plays the crucial role of providing a high specific capacity. However, it also induces an irreversible oxygen release and accelerates the layered-to-spinel phase transformation and capacity fading. Here, it is shown that surface doping of vanadium (V5+) cations into LLC material suppresses both the irreversible oxygen release and undesirable phase transformation, resulting in the improvement of capacity retention. The V-doped LLC shows a high discharge capacity of 244.3 +/- 0.8 mAh g(-1) with 92% retention after 100 cycles, whereas LLC delivers 233.6 +/- 1.1 mAh g(-1) with 74% retention. Furthermore, the average discharge voltage of V-doped LLC drops by only 0.33 V after 100 cycles, while LLC exhibits 0.43 V of average discharge voltage drop. Experimental and theoretical investigations indicate that doped V-doping increase the transition metal-oxygen (TM-O) covalency and affect the oxidation state of peroxo-like (O-2)(n-) species during the delithiation process. The role of V-doping to make the oxygen redox reversible in LLC materials for high-energy density Li-ion batteries is illustrated here.

Automated summary

Li-excess layered cathode (LLC) materials have high theoretical specific capacity, but oxygen redox reaction may cause irreversible oxygen release and phase transformation. Doping vanadium (V) into LLC suppresses these issues and improves capacity retention.