期刊
CHEMELECTROCHEM
卷 8, 期 4, 页码 735-744出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.202001586
关键词
cavity microelectrode; cyclic voltammetry; electrocatalysis; nanoparticles; square wave voltammetry
Cavity microelectrodes (CMEs) provide a valuable platform for evaluating the electrocatalytic performance of micro- and nanoparticulate materials; experiments show capacitive distortion increases with powder surface area, but faradaic response mainly occurs on the first layer of the powder load, cyclic voltammetry and square wave voltammetry (SWV) are suitable for discriminating faradaic processes at CMEs.
Cavity microelectrodes (CMEs) offer a valuable platform to evaluate the electrocatalytic performance of micro- and nanoparticulate materials. The technical factors and physicochemical processes affecting the electrochemical response at CMEs are to be recognized; specifically, the accessibility of redox species to the electrocatalyst surface. With this aim, the voltammetric response of CMEs is investigated through a joint experimental and theoretical approach including a comparative study of cyclic and square wave voltammetry (SWV). Experiments reveal a capacitive distortion of the response that increases with the powder surface area, but with a faradaic response analogous to that of recessed or inlaid microdisks, that is, with electrochemical reactions occurring essentially on the first layer of the powder load. We show that SWV is well suited to discriminate faradaic processes at CMEs and we present accurate mathematical expressions to describe it. These results provide guidelines for the design and analysis of CME voltammetric measurements.
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