Effect of Iodine Filler on Photoisomerization Kinetics of Photo-Switchable Thin Films Based on PEO-BDK-MR

We report the effect of an iodine filler on photoisomerization kinetics of photo-switchable PEO-BDK-MR thin films. The kinetics of photoisomerization and time progression of PEO-BDK-MR/I-2 nanocomposite thin films are investigated using UV-Vis, FTIR spectroscopies, and modified mathematical models developed using new analytical methods. Incorporating iodine filler into the PEO-BDK-MR polymeric matrix enhances the isomerization energy barrier and considerably increases the processing time. Our outcomes propose that enhanced photoisomerized and time processed (PEO-BDK-MR)/I-2 thin films could be potential candidates for a variety of applications involving molecular solar thermal energy storage media.

Automated summary

Incorporating an iodine filler into PEO-BDK-MR thin films enhances the isomerization energy barrier and significantly increases the processing time, making them potential candidates for applications involving molecular solar thermal energy storage media.