期刊
POLYMERS
卷 13, 期 5, 页码 -出版社
MDPI
DOI: 10.3390/polym13050792
关键词
polymerizable ionic liquids; ionogel; structure– property relationship; ionic conductivity; ionic liquids; lithium-ion battery; solid state electrolyte; solid-state-battery
资金
- Deutsche Forschungsgemeinschaft (Sachbeihilfe) [HO 5266/1-2]
Increasing side chain length of the studied ammonium-based polymerized ionic liquids results in lower glass transition temperatures and higher ionic conductivity values. However, the addition of conducting salt to the polymer membranes decreases both the glass transition temperatures and the ionic conductivity values, while higher lithium-ion mobility is observed in samples with higher conducting salt content.
Eight new polymerized ammonium-based ionic liquids were prepared as thin membrane films and evaluated within the scope of their usage in lithium-ion batteries. The focus of this work is to get a better understanding of the influence of structural modifications of the monomers on the polymerized materials. Further, different concentrations of a lithium-ion conducting salt were applied in order to receive an optimized combination of monomer structure and lithium salt concentration. It was found that an increased side chain length of the studied ammonium-based polymerized ionic liquids leads to a reduction in glass transition temperatures and increased ionic conductivity values. As a result of the addition of conducting salt to the PIL membranes, the glass transition temperatures and the ionic conductivity values decreases. Nevertheless, PFG-NMR reveals a higher lithium-ion mobility for a sample with higher conducting salt content.
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