4.7 Article

Impact of Water and UV Irradiation on Nonwoven Polylactide/Natural Rubber Fiber

期刊

POLYMERS
卷 13, 期 3, 页码 -

出版社

MDPI
DOI: 10.3390/polym13030461

关键词

polylactide; non-woven fiber; natural rubber; hydrolytic degradation; UV-irradiation; electrospinning

资金

  1. Ministry of Science and Higher education of the Russian Federation [1201253305]

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The addition of natural rubber to a polylactide matrix did not significantly impact the water absorption of fibers, with a slight increase in melt flow rate observed. Fiber samples from all compositions retained the propensity for photo- and hydrolytic degradation after degradation in distilled water and UV irradiation.
A nonwoven fiber made of polylactide/natural rubber with a rubber content from 0 to 15 wt.% was obtained by electrospinning from a solution. The water sorption test showed that the addition of natural rubber into the polylactide matrix did not significantly affect the degree of water absorption of the fibers, which was in the range of 48.9-50.6%. The melt flow rate only increased by 0.5 g/10 min at a content of 15 wt.% natural rubber. The thermal characteristics after 120 days of degradation in distilled water and UV irradiation (50 h) at a wavelength of 365 nm were determined using differential scanning calorimetry. Changes in the values of the phase transition temperatures and the degree of crystallinity were determined. It was determined that the fiber samples from all compositions retained the propensity for photo- and hydrolytic degradation.

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