期刊
ACS CATALYSIS
卷 11, 期 5, 页码 2701-2714出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.0c04586
关键词
alcohol oxidation; green chemistry; hydrogen peroxide; palladium-iron; reactive oxygen species; noninnocent solvent
资金
- Haldor Topsoe
- EPSRC
- National Natural Science Foundation of China [21991153, 21991150, 21872163, 22072090]
- UCL [PR16195]
- EPSRC [EP/P019951/1] Funding Source: UKRI
The study demonstrates that bimetallic Pd-Fe catalysts supported on TiO2 are highly effective in oxidizing benzyl alcohol to benzaldehyde through the in situ production of H2O2. The enhanced activity of Pd-Fe catalysts, compared to other analogues, can be attributed to their bifunctionality for synthesizing H2O2 and catalyzing the production of oxygen-based radical species.
Bimetallic Pd-Fe catalysts supported on TiO2 are shown to be highly effective toward the selective oxidation of benzyl alcohol to benzaldehyde via the in situ production of H2O2 from molecular H-2 and O-2, under conditions where no reaction is observed with molecular O-2 alone. The rate of benzyl alcohol oxidation observed over supported Pd-Fe nanoparticles is significantly higher than those of either Pd-Au or Pd-only analogues. This enhanced activity can be attributed to the bifunctionality of the Pd-Fe catalyst to both synthesize H2O2 and catalyze the production of oxygen-based radical specie,s as indicated by an electron paramagnetic resonance analysis. Further studies also reveal the noninnocent nature of the solvent, resulting in the propagation of radical generation pathways.
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