4.8 Article

Experimental evidence for the existence of a second partially-ordered phase of ice VI

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Summary: Ice XIX, a new partially antiferroelectrically ordered polymorph derived from ice VI, has been characterized structurally and thermally. Its synthesis involves the use of a DCl-doped D2O/H2O mixture, with a small H2O fraction enhancing nucleation kinetics. The transition from ice XIX to its sibling ice XV has been observed, representing the first order-order transition known in ice physics.

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