4.8 Article

Automatic light-adjusting electrochromic device powered by perovskite solar cell

期刊

NATURE COMMUNICATIONS
卷 12, 期 1, 页码 -

出版社

NATURE RESEARCH
DOI: 10.1038/s41467-021-21086-7

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资金

  1. Shenzhen fundamental research programs [JCYJ20170817111349280, JCYJ20170412152922553, JCYJ20180305180635082]
  2. SUSTech [Y01256114]
  3. High-level university construction fund for SUSTech [G01256018]
  4. National Key Research and Development Project from the Ministry of Science and Technology of China [2016YFA0202400, 2016YFA0202404]
  5. Peacock Team Project from Shenzhen Science and Technology Innovation Committee [KQTD2015033110182370]

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The study introduces a novel all-in-one gel electrochromic device powered by perovskite solar cells, which can automatically adjust light absorption in real-time based on surrounding light intensity. With high stability and energy conversion efficiency, the device shows significant potential for applications as modern intelligent windows.
Electrochromic devices can modulate their light absorption under a small driving voltage, but the requirement for external electrical supplies causes response-lag. To address this problem, self-powered electrochromic devices have been studied recently. However, insensitivity to the surrounding light and unsatisfactory stability of electrochromic devices have hindered their critical applications. Herein, novel perovskite solar cell-powered all-in-one gel electrochromic devices have been assembled and studied in order to achieve automatic light adjustment. Two alkynyl-containing viologen derivatives are synthesized as electrochromic materials, the devices with very high stability (up to 70000 cycles) serves as the energy storage and smart window, while the perovskite solar cell with power-conversion-efficiency up to 18.3% serves as the light detector and power harvester. The combined devices can automatically switch between bleached and colored state to adjust light absorption with variable surrounding light intensity in real-time swiftly, which establish significant potentials for applications as modern all-day intelligent windows. The requirement for external electric supplies has significantly limited the application of electrochromic devices in modulating light absorption as smart windows. Here, the authors report automatic switching perovskite solar cells-powered all-in-one gel electrochromic device in response to surrounding light intensity in real-time.

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