4.7 Article

Oil miscible phosphonium-phosphate ionic liquid as novel antiwear and antipitting additive for low-viscosity rear axle lubricants

期刊

WEAR
卷 466, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.wear.2020.203588

关键词

Ionic liquids; Lubricant additives; Micropitting; Gear; Rolling contact fatigue

资金

  1. Vehicle Technologies Office of Office of Energy Efficiency and Renewable Energy of U.S. Department of Energy (DOE)
  2. Tank Automotive Research of Development and Engineering Center (TARDEC) of U.S. Army of U.S. Department of Defense (DoD)
  3. Scientific User Facilities Division, Office of DOE-BES
  4. U.S. Department of Energy [DEAC05-00OR22725]

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This study demonstrated the feasibility of using a phosphonium phosphate ionic liquid as an anti-wear and anti-pitting additive for rear axle lubricant. The results showed effective surface protection for wear and micro-cracking, leading to the production of low-viscosity gear oils with superior rolling contact fatigue mitigation. Full-scale hub dynamometer tests further confirmed the improved power output and torque generation of the IL-containing gear oils compared to commercial benchmarks.
This study explored the feasibility of using a phosphonium phosphate ionic liquid as a candidate anti-wear and anti-pitting additive for rear axle lubricant. This particular IL was first added to a VHVI8 base oil at 2-3% concentration and demonstrated effective surface protection for wear and micro-cracking under rolling-sliding contacts. The promising results directed to a step further to produce a series of IL-containing low-viscosity (about a half of SAE 75W-90) fully formulated gear oils. Selected IL-containing experimental oils showed superior mitigation of rolling contact fatigue to a commercial SAE 75W-90 gear oil in bench-scale rolling-sliding tests. Full-scale hub dynamometer tests were then conducted and demonstrated more than 3% power output and torque generation for an IL-containing low-viscosity gear oil benchmarked against commercial baselines.

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