Using a natural chlorite as catalyst in chemical recycling of waste plastics: Hydrolytic depolymerization of poly-[bisphenol A carbonate] promoted by clinochlore

The present study describes the first example of utilization of a natural clay mineral as catalyst in a process addressed to chemical valorization of poly-[bisphenol A carbonate] (PC; (1)) wastes. A natural clinochlore was investigated for the first time as the catalyst of the hydrolysis reaction of 1, a potential route to chemical recycling of wastes of this polymeric material. At 473 K, in tetrahydrofuran (THF) as the solvent, the mineral promoted effectively the depolymerization (up to 99%, after 6 h) of 1 by H2O and the selective (similar to 99%) regeneration of the monomer bisphenol A (BPA, (2)). Temperature, catalyst loading, reaction time, H2O/PC weight ratio affected markedly the productivity of the process. The role of the catalyst was also focused: the experimental data showed that the exposed brucite-like sheets of clinochlore are involved in the hydrolysis reaction and take active part in promoting the depolymerization process. (C) 2020 Elsevier Ltd. All rights reserved.

Automated summary

This study investigates the use of natural clay mineral as a catalyst for the chemical valorization of poly-[bisphenol A carbonate] wastes. It was found that the mineral promoted depolymerization of the waste material effectively and achieved selective regeneration of the monomer. Factors such as temperature, catalyst loading, and H2O/PC weight ratio significantly influenced the productivity of the process.