期刊
VACUUM
卷 185, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.vacuum.2020.109998
关键词
Template assisted synthesis; Double reflux mechanism; M41/m-Co3O4; Cyclic voltammetry; Specific capacitance
资金
- SNR Sons charitable trust, Coimbatore
- CSIR-HRDG [08/757/(0001)/2020 EMR-I]
- National Science Council
- Ministry of Education, Taiwan
- Ministry of Science and Technology, Taiwan [MOST 107-2113-M-027-005-MY3]
The cobalt oxide nanostructures prepared using mesoporous silica template were successfully applied in electrochemical supercapacitors, showing impressive specific capacitance and cycling stability. The nanobuds were studied in 1 M KOH electrolyte solution for cyclic voltammetry and electro impedance spectroscopy, demonstrating efficient charge transfer mechanism and rapid ion diffusion.
The supercapacitors are a static energy storage device that can stock and supply energy at an enhanced rate. They exhibit a high-power density coupled with long cycling life which are highly significant for the superior energy storage platforms. In such a way, we prepared cobalt oxide nanostructures using mesopomus silica (M41) as template and used as an electrochemical supercapacitor. The synthesized M41/m-Co3O4 nanobuds were thoroughly characterized for its crystallinity, morphology, composition and surface area. The M41/m-Co3O4 nanobuds were utilized as a modified electrode material in the electrochemical system and studied in 1 M KOH as an electrolyte solution for cyclic voltammetry (CV) and electro impedance spectroscopy studies (EIS). The EIS ensures the effortless charge transfer mechanism which facilitates rapid ion diffusion leading to the high accumulation of charges. Thus, an impressive specific capacitance of 228.87 F g(-1) with excellent cycling stability of 87.5% over 1000 cycles was achieved through our investigation.
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