期刊
TOPICS IN CATALYSIS
卷 64, 期 5-6, 页码 316-327出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-021-01412-5
关键词
CO2 hydrogenation; Light olefins; Fe-based catalysts; In2O3; SAPO-34; Catalysts bed configuration
资金
- Thailand Research Fund
- Kasetsart University [RSA6280007]
- Center of Excellence on Petrochemical and Materials Technology (PETROMAT)
- Nanotechnology Center (NANOTEC), NSTDA
- Ministry of Science and Technology, Thailand, through its program of Research Network of NANOTEC (RNN)
- Vidyasirimedhi Institute of Science and Technology
- Kasetsart University Research and Development Institute (KURDI) through its program of Development of Advance Researcher Competence System for Competitiveness in Agriculture and Food [FF(KU)25.64]
- Program Management Unit for Human Resources AMP
- Institutional Development, Research and Innovation [B05F630097]
- Thailand Toray Science Foundation
Direct CO2 conversion to light olefins is an opportunity to reduce emissions and generate revenue, but the lack of efficient catalysts hinders industrial scale implementation. A new composite catalyst system has been developed to enhance light olefins yield, offering a potential solution to this barrier.
Direct CO2 conversion to light olefins offers a chance to reduce CO2 emission with generating the revenue. However, a lack of efficient catalysts is a barrier for promoting this technology to an industrial scale. Here, we report a new catalytic system using a composite catalyst containing In2O3/SAPO-34 and Fe-Co/K-Al2O3 to enhance the light olefins yield. The effect of catalysts bed configuration including a physical mixture of In2O3/SAPO-34 with Fe-Co/K-Al2O3 (M-InS/Fe-Co), a dual-layer packing of In2O3/SAPO-34 followed by Fe-Co/K-Al2O3 (T-InS/B-FeCo) and a dual-layer packing of Fe-Co/K-Al2O3 above In2O3/SAPO-34 (T-FeCo/B-InS) is investigated. The M-InS/Fe-Co and T-FeCo/B-InS catalysts show a light olefins yield of 11.5 and 16.2% which are lower than that (18.9%) of the single Fe-Co/K-Al2O3 catalyst. A drastic reduction in the BET surface area (42 m(2) g(-1)) of M-InS/Fe-Co catalyst compared to its theoretical value of 198 m(2) g(-1) is observed, suggesting the pores blockage. The T-InS/B-FeCo composite catalyst achieves a state-of the art light olefins yield of 21.5% due to a selective CO2 conversion to light olefins over In2O3/SAPO-34 and a highly active CO2 conversion to hydrocarbon over Fe-Co/K-Al2O3 which further converts the remaining CO2 from the former catalyst bed to light olefins and other hydrocarbon products until equilibrium CO2 conversion is reached.
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