Using excitation-emission matrix fluorescence to evaluate the performance of water treatment plants for dissolved organic matter removal

This study is aimed at assessing the performance of water treatment plants (both wastewater and drinking water treatment plants) for dissolved organic matter (DOM) removal using excitation-emission matrix fluorescence (EEMF) as the monitoring technique. The influent from the wastewater treatment plant (WWTP) of Burgos (Spain) is characterized from the presence of protein-like peaks (T1 and T2) and humic-like peaks (A and C), T2 and A showing the highest fluorescence intensity. The percentages of total removal in the effluent were in the following order: peak T1 (65%) > peak A (45%) > peak C (34%) > peak T2 (26%). The humic-like peaks were the most removed at the primary sedimentation stage, whereas peak T1 was by far the most removed in the biological reactor. Protein-like peaks T1 and T2 experienced a slight increase in the final effluent in comparison to their fluorescence at the previous stage (the exit of the biological reactor), an increase that can be explained by the release of SMP (soluble microbial products) from the biomass in the secondary clarifier. A poor correlation was obtained between peak T2 fluorescence and COD, BOD (r(2) = 0.34-0.38). The natural water from the Uzquiza reservoir in Burgos (Spain) is characterized by the only presence of humic substances: a majority peak A (fulvic-like) and a weak peak C (humic-like). The whole fluorescent DOM was removed by coagulation-flocculation but a low fluorescence peak T2 appeared at the final stage, coming from protein-like SMPs released by the biomass attached to the filters. (C) 2020 Elsevier B.V. All rights reserved.

Automated summary

This study assessed the performance of water treatment plants in removing dissolved organic matter (DOM), revealing different removal rates for different fluorescence peaks at a WWTP in Burgos, Spain. Coagulation-flocculation effectively removed the entire fluorescent DOM in the Uzquiza reservoir, but residual protein-like SMPs were observed in the final stage.