4.7 Article

In2O3 nanocubes modified with RuO2 for detection of TXM vapors containing benzyl group

期刊

SENSORS AND ACTUATORS B-CHEMICAL
卷 338, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2021.129731

关键词

In2O3 nanocubes; RuO2; Surface modification; Benzyl gases; Selectivity

资金

  1. Key Program of the Chinese Academy of Sciences [KFZD-SW-320]
  2. National Natural Science Foundation of China [21471147]
  3. Opened Fund of the State Key Laboratory on Integrated Optoelectronics [IOSKL2017KF08]

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The sensing properties of RuO2-modified In2O3 materials are significantly enhanced, with a rapid increase in response to vapor containing benzyl group. The response to mesitylene increases by 36 times at 255 degrees Celsius, with a noticeable decrease in optimum operating temperature.
Indium oxide (In2O3) nanocubes modified by ruthenium oxide (RuO2) on the surface are successfully prepared through hydrothermal method, calcination and impregnation in turn. The sensing properties of RuO2-modified In2O3 sensing material are significantly enhanced even with low loading amount. The response values of RuO2-modified In2O3 sensing material to TXM vapor containing benzyl group (including toluene, xylene and mesitylene) increase rapidly when compared to various volatile organic compounds (VOCs). Therein the RuO2-modified In(2)O(3)sensor displays a 36-times increase in response value to mesitylene (100 ppm) in contrast to unmodified one at 255 degrees C. The optimum operating temperature (OOT) decreases obviously from 375 degrees C of pristine In2O3 one. The gas sensing enhancement mechanism can be explained by electronic and chemical sensitization. However, the reason for selectivity change will be (temporarily) investigated further later.

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