期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 331, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2020.129418
关键词
Carbazole based AIEE chemosensor; Hg-2(+)/Al(3)(+)detection; Nano-level determination; food/environmental sample analysis; Live-cell imaging; Logic gate
资金
- National Natural Science Foundation of China [21801144, 21776143, 51702178]
- Ji Nan Science & Technology Bureau [2019GXRC021]
- Natural Science Foundation of Shandong Province [ZR2017LB009]
- Program for College Students' Innovation and Entrepreneurship Training of Qilu University of Technology
- Youth Innovative Talents Recruitment and Cultivation Program of Shandong Higher Education
- Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province
The newly designed CBS serves as a colorimetric/fluorimetric chemosensor for selective and sensitive detection of Hg2+ and Al3+ in aqueous media, with low detection limits and potential applications in environmental and biological fields.
A new simple carbazole Schiff base (CBS) with typical aggregation-induced emission enhancement (AIEE) property was designed and synthesized based on carbaldehyde and 2-hydroxybenzohydrazide units, which was successfully utilized as a new dual-responsive colorimetric/fluorimetric chemosensor for highly selective and sensitive turn-off' fluorescence detection of Hg2+ and turn-on fluorescence sensing Al3+ in near-perfect aqueous media based on metal chelation mechanism. The low detection limits of CBS for Hg2+ and Al3+ were respectively determined to be 14.7 nM and 47.2 nM, far lower than the WHO guidelines for drinking water, which permitted its nano-level determination in real samples. The CBS for Hg2+/Al3+ sensing displayed outstanding advantages of pH stability, excellent reversibility, ultra-fast response, stronger anti-interference capability and lower cytotoxicity compared with other related chemosensors. The binding mode of CBS with Hg2+/Al3+ was determined to be a 1:1 complexation stoichiometry using Job's plot analysis and fluorescent titration curve, which further confirmed by FTIR and H-1 NMR analysis. Due to its good colorimetric/fluorimetric properties, a simple cost-effective portable on-site test strip was developed that allows for visual, fast, reliable and convenient detecting Hg2+/Al3+ in environmental analysis. Moreover, chemosensor CBS has successful application in building molecular logic gates. Furthermore, the CBS was successfully applied in soil, environmental water, and food samples analysis and live-cell imaging, demonstrated its great potentials in environmental and biological applications.
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