4.8 Article

Continuous electrochemical water splitting from natural water sources via forward osmosis

出版社

NATL ACAD SCIENCES
DOI: 10.1073/pnas.2024855118

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forward osmosis; water splitting; seawater; hydrogen; solar

资金

  1. Department of the Navy, Office of Naval Research [N00014-20-1-2418]
  2. Herchel Smith Graduate Fellowship in the Sciences

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This study presents a method of utilizing impure water sources for electrochemical water splitting by leveraging forward osmosis, maintaining a concentration gradient that induces water flow and allows for water splitting without pretreatment and minimal energy efficiency losses.
Electrochemical water splitting stores energy as equivalents of hydrogen and oxygen and presents a potential route to the scalable storage of renewable energy. Widespread implementation of such energy storage, however, will be facilitated by abundant and accessible sources of water. We describe herein a means of utilizing impure water sources (e.g., saltwater) for electrochemical water splitting by leveraging forward osmosis. A concentration gradient induces the flow of water from an impure water source into a more concentrated designed electrolyte. This concentration gradient may subsequently be maintained by water splitting, where rates of water influx (i.e., forward osmosis) and effective outflux (i.e., water splitting) are balanced. This approach of coupling forward osmosis to water splitting allows for the use of impure and natural sources without pretreatment and with minimal losses in energy efficiency.

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