期刊
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
卷 20, 期 3, 页码 357-367出版社
SPRINGERNATURE
DOI: 10.1007/s43630-021-00023-z
关键词
Perovskite solar cells; Anti solvent; Surface defects; Bidentate ligand; β -Diketone Lewis base
资金
- JSPS KAKENHI [18H02079]
- Egyptian Ministry of Higher Education & Scientific Research
- Grants-in-Aid for Scientific Research [18H02079] Funding Source: KAKEN
The introduction of two beta-diketone passivators successfully reduces the surface defects generated from under coordinated Pb2+ ions in CH3NH3PbI3 perovskite films, leading to an enhancement in the photovoltaic performance and stability of the PSCs.
Hybrid organic-inorganic perovskite solar cells (PSCs) are promising new generations of solar cells, which is low in cost with high power conversion efficiency (PCE). However, PSCs suffer from structural defects generated from the under coordinated ions at the surface, which limits their photovoltaic performances. Herein we report, two beta-diketone Lewis base additives 2,4-pentanedione and 3-methyl-2,4-nonanedione within the chlorobenzene anti-solvent to passivate the surface defects generated from the under coordinated Pb2+ ions in CH3NH3PbI3 perovskite films. The incorporation of the two beta-diketone passivators could successfully enhance the open-circuit voltage of the PSCs by 52 mV and 17 mV for 3-methyl-2,4-nonanedione and 2,4-pentanedione, respectively, with improved PCE by 45% for 3-methyl-2,4-nonanedione compared to the pristine PSC. This enhancement in the photovoltaic performance of the PSCs can be attributed to passivation of the defects through the interaction between two carbonyl groups of the beta-diketone Lewis base additives and the under coordinated Pb2+ defects in the perovskite film, which improved the PSCs PCE and stability.
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