期刊
ORGANIC LETTERS
卷 23, 期 5, 页码 1664-1668出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c00077
关键词
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资金
- Science and Education Research Board [CRG/2019/000025]
- Department of Biotechnology [BT/INF/22/SP23026/2017]
- CSIR-New Delhi
In this study, a total synthesis strategy for the structurally unique fungal glycolipid fusaroside was reported, with a proposed revision in its structure, particularly regarding the position of olefins in the lipid chain.
Herein, we report a strategy for the total synthesis of a structurally unique fungal glycolipid fusaroside. The first total synthesis of the proposed structure involved construction of the complex, branched lipid chain having a variety of alkenes with E stereochemistry and attachment of the masked alpha,beta-unsaturated beta-keto acid at the O-4 position of trehalose as key steps. We propose a revision in the structure of fusaroside, particularly the position of olefins in the lipid chain.
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